Showing posts with label process. Show all posts
Showing posts with label process. Show all posts

Friday, February 19, 2010

Saponification

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a process in which ESTERS are hydrolysed by the action of acids, alkalis, boiling with water or superheated steam. If alkalis are used then SOAPS are produced and this is the origin of the term (sapo is the Latin for soap).

Taken from Dictionary of Science

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Saponification is the hydrolysis of an ester under basic conditions to form an alcohol and the salt of a carboxylic acid (carboxylates). Saponification is commonly used to refer to the reaction of a metallic alkali (base) with a fat or oil to form soap. Saponifiable substances are those that can be converted into soap.


Sodium hydroxide (NaOH) is a caustic base. If NaOH is used a hard soap is formed, whereas when potassium hydroxide (KOH) is used, a soft soap is formed. Vegetable oils and animal fats are fatty esters in the form of triglycerides. The alkali breaks the ester bond and releases the fatty acid salt and glycerol. If necessary, soaps may be precipitated by salting it out with saturated sodium chloride. The saponification value is the amount of base required to saponify a fat sample.


In a classic laboratory procedure the triglyceride trimyristin is obtained by extracting nutmeg with diethyl ether. Saponification to the sodium salt of myristic acid takes place with NaOH in water. The acid itself can be obtained by adding dilute hydrochloric acid.

Taken from Wikipedia



Wednesday, January 13, 2010

Radioactivity


the giving out of particles (known as α or β particles and γ rays) by unstable substances that are disintegrating.

Taken from Dictionary of Science

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Radioactive decay is the process in which an unstable atomic nucleus spontaneously loses energy by emitting ionizing particles and radiation. This decay, or loss of energy, results in an atom of one type, called the parent nuclide transforming to an atom of a different type, named the daughter nuclide. For example: a carbon-14 atom (the "parent") emits radiation and transforms to a nitrogen-14 atom (the "daughter"). This is a stochastic process on the atomic level, in that it is impossible to predict when a given atom will decay, but given a large number of similar atoms the decay rate, on average, is predictable.


The SI unit of activity is the becquerel (Bq). One Bq is defined as one transformation (or decay) per second. Since any reasonably-sized sample of radioactive material contains many atoms, a Bq is a tiny measure of activity; amounts on the order of GBq (gigabecquerel, 1 x 109 decays per second) or TBq (terabecquerel, 1 x 1012 decays per second) are commonly used. Another unit of radioactivity is the curie, Ci, which was originally defined as the amount of radium emanation (radon-222) in equilibrium with of one gram of pure radium, isotope Ra-226. At present it is equal, by definition, to the activity of any radionuclide decaying with a disintegration rate of 3.7 × 1010 Bq. The use of Ci is presently discouraged by the SI.


Taken from Wikipedia

Tuesday, January 12, 2010

Xerography


a copying process in which an ELECTROSTATIC image is formed on a surface when exposed to an optical image. A powder mix of GRAPHITE and a thermoplastic resin of opposite charge to the electrostatic image is dusted on to the surface and the particles cling to the charged areas. The image is then transferred to a sheet of paper; again through use of opposite charges, and the image is fixed by heat.

Taken from Dictionary of Science